| Summary |
The aim of this study, carried out within the frame of the MACPoll project, is to assess if the NO2-B4 AlphaSense sensor meets the data quality objective (DQO) set in the European Air Quality Directive for NO2 indicative measurements. The report presents the evaluation of the performances and determination of the laboratory and field measurement uncertainty, compared to uncertainties fixed by the DQO, namely 25% at 100 nmol/mol, for hourly NO2 indicative measurements. The laboratory evaluation shows that the NO2-B4 sensor give a linear answer with changing NO2 concentrations. However, the tested sensors were suffering from an important long-term drift and a huge hysteresis effect against humidity and temperature changes. Among ozone (O3), carbon monoxide (CO), carbon dioxide (CO2), nitrogen monoxide (NO), ammonia (NH3) and sulphur dioxide (SO2), the sensor showed a high sensitivity to ozone (about 120 %). Moreover, the NO2-B4 was found slightly sensitive to NH3 while it was independent from the other species. The NO2-B4 sensor did suffer from short-term drift but did not show any hysteresis effect when NO2 levels change. The sensor appeared to be slightly influenced by wind velocity. Conversely, power supply (220 V) did not appear to have an effect on the sensor response likely because of the quality of the DC transformer used in laboratory. In our current laboratory set-up, it was not possible to test the effect of pressure. A multi-linear equation model was established in laboratory based on the aging of calibration, O3, temperature and relative humidity to estimate NO2. Using this model, the measurement uncertainty of NO2-B4 sensors was found lower than the DQO provided that the O3 contribution after correction was lower than 5%. Using a simple linear calibration did not allow reaching the DQO of the Directive. The sensors used during the field tests were first calibrated in laboratory experiments against reference NO2 gas mixtures. Unfortunately, the field campaign took place in late winter - summer period when NO2 was lower than O3 in ambient air. Additionally, since NO2-B4 sensor is sensitive to both species, NO2 was obfuscated by O3 that made impossible to evaluate the final field uncertainty. The noise was found to be high during the whole field campaign preventing from obtaining valid measurements. Therefore, the model established with the laboratory experiments could not be verified in field. According to this study, the application of the sensor as indicative method for NO2 measurement is not fully validated. In fact, the sensor is lacking field confirmation of the laboratory results which that suggest the need of sensor data correction for long term drift, O3 cross-sensitivity, temperature and relative humidity. Even though the NO2-B4 sensor is not fully selective, it produces repeatable values that can be useful provided that a correction algorithms is developed to correctly estimate NO2 using influencing variables to solve the sensitivity, selectivity and stability drawback of sensor measurements. |